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Unusual cyanide and methyl binding modes at a dicobalt macrocycle following acetonitrile C–C bond activation
This communication describes the C–C bond activation of acetonitrile and the trapping of the methyl and cyanide fragments by macrocyclic, dicobalt complexes. Both products display unique structural features as a result of the constraints imposed by the macrocycle. The bridged species [((3)PDI(2))Co(...
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| Veröffentlicht in: | Chem Commun (Camb) |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7442599/ https://ncbi.nlm.nih.gov/pubmed/32696777 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc03521a |
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