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Alkyl halides as both hydride and alkyl sources in catalytic regioselective reductive olefin hydroalkylation

Among the plethora of catalytic methods developed for hydrocarbofunctionalization of olefins to date, reactions that regioselectively install a functionalized alkyl unit at the 2-position of a terminal unactivated C=C bond to afford branched products are scarce. Here, we show that a Ni-based catalys...

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Vydáno v:Nat Commun
Hlavní autoři: Chen, Xianxiao, Rao, Weidong, Yang, Tao, Koh, Ming Joo
Médium: Artigo
Jazyk:Inglês
Vydáno: Nature Publishing Group UK 2020
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7673021/
https://ncbi.nlm.nih.gov/pubmed/33203895
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-19717-6
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