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Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds

Investigations into the selectivity of intermolecular alkyl radical additions to C–O- vs. C–C-double bonds in α,β-unsaturated carbonyl compounds are described. Therefore, a photoredox-initiated radical chain reaction is explored, where the activation of the carbonyl-group through an in situ generate...

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Bibliografische gegevens
Gepubliceerd in:Chem Sci
Hoofdauteurs: Paulisch, Tiffany O., Strieth-Kalthoff, Felix, Henkel, Christian, Pitzer, Lena, Guldi, Dirk M., Glorius, Frank
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Royal Society of Chemistry 2019
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7640737/
https://ncbi.nlm.nih.gov/pubmed/33209246
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04846d
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