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Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds
Investigations into the selectivity of intermolecular alkyl radical additions to C–O- vs. C–C-double bonds in α,β-unsaturated carbonyl compounds are described. Therefore, a photoredox-initiated radical chain reaction is explored, where the activation of the carbonyl-group through an in situ generate...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7640737/ https://ncbi.nlm.nih.gov/pubmed/33209246 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04846d |
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