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Ligand-Controlled Reactivity and Cytotoxicity of Cyclometalated Rhodium(III) Complexes

We report the synthesis, characterisation and cytotoxicity of six cyclometalated rhodium(III) complexes [Cp(X)Rh(C^N)Z](0/+), in which Cp(X) = Cp*, Cp(ph), or Cp(biph), C^N = benzo[h]quinoline, and Z = chloride or pyridine. Three x-ray crystal structures showing the expected “piano-stool” configurat...

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Detalhes bibliográficos
Publicado no:Eur J Inorg Chem
Main Authors: Zhang, Wen-Ying, Bridgewater, Hannah E., Banerjee, Samya, Soldevila-Barreda, Joan J., Clarkson, Guy J., Shi, Huayun, Imberti, Cinzia, Sadler, Peter J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7610438/
https://ncbi.nlm.nih.gov/pubmed/33776557
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201901055
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