Catalase Involved in Oxidative Cyclization of the Tetracyclic Ergoline of Fungal Ergot Alkaloids

A dedicated enzyme for the formation of the central C ring in the tetracyclic ergoline of clinically important ergot alkaloids has never been found. Herein, we report a dual role catalase (EasC), unexpectedly using O(2) as the oxidant, that catalyzes the oxidative cyclization of the central C ring f...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Yao, Yongpeng, An, Chunyan, Evans, Declan, Liu, Weiwei, Wang, Wei, Wei, Guangzheng, Ding, Ning, Houk, K. N., Gao, Shu-Shan
Format: Artigo
Sprog:Inglês
Udgivet: 2019
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7592905/
https://ncbi.nlm.nih.gov/pubmed/31621316
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10217
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