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Catalase Involved in Oxidative Cyclization of the Tetracyclic Ergoline of Fungal Ergot Alkaloids
A dedicated enzyme for the formation of the central C ring in the tetracyclic ergoline of clinically important ergot alkaloids has never been found. Herein, we report a dual role catalase (EasC), unexpectedly using O(2) as the oxidant, that catalyzes the oxidative cyclization of the central C ring f...
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| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7592905/ https://ncbi.nlm.nih.gov/pubmed/31621316 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10217 |
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