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Rate-Limiting Steps in the Intramolecular C–H Activation of Ruthenium N-Heterocyclic Carbene Complexes

[Image: see text] Ruthenium (II) complexes with N-heterocyclic carbenes (NHC) are commonly used as efficient catalysts in hydrogenation of olefins with simultaneous intramolecular C–H activation. Using the DFT approach, we have investigated the entire hydrogenation reaction pathway for four new pote...

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Publicat a:J Phys Chem A
Autors principals: Młodzikowska-Pieńko, Katarzyna, Trzaskowski, Bartosz
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7590980/
https://ncbi.nlm.nih.gov/pubmed/32293892
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.0c01354
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