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Backbone tuning in indenylidene–ruthenium complexes bearing an unsaturated N-heterocyclic carbene
The steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)(2)(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electro...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3002078/ https://ncbi.nlm.nih.gov/pubmed/21160916 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.128 |
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