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Planar Cyclopenten‐4‐yl Cations: Highly Delocalized π Aromatics Stabilized by Hyperconjugation

Theoretical studies predicted the planar cyclopenten‐4‐yl cation to be a classical carbocation, and the highest‐energy isomer of C(5)H(7) (+). Hence, its existence has not been verified experimentally so far. We were now able to isolate two stable derivatives of the cyclopenten‐4‐yl cation by reacti...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
में प्रकाशित:Angew Chem Int Ed Engl
मुख्य लेखकों: Nees, Samuel, Kupfer, Thomas, Hofmann, Alexander, Braunschweig, Holger
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: John Wiley and Sons Inc. 2020
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC7589364/
https://ncbi.nlm.nih.gov/pubmed/32701182
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009644
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