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Telescoped Continuous Flow Synthesis of Optically Active γ-Nitrobutyric Acids as Key Intermediates of Baclofen, Phenibut, and Fluorophenibut

[Image: see text] The two-step flow asymmetric synthesis of chiral γ-nitrobutyric acids as key intermediates of the GABA analogues baclofen, phenibut, and fluorophenibut is reported on a multigram scale. The telescoped process comprises an enantioselective Michael-type addition facilitated by a poly...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Ötvös, Sándor B., Llanes, Patricia, Pericàs, Miquel A., Kappe, C. Oliver
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7573919/
https://ncbi.nlm.nih.gov/pubmed/33026815
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c03100
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