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Multigram-scale flow synthesis of the chiral key intermediate of (–)-paroxetine enabled by solvent-free heterogeneous organocatalysis

The catalytic enantioselective synthesis of the chiral key intermediate of the antidepressant (–)-paroxetine is demonstrated as a continuous flow process on multi-gram scale. The critical step is a solvent-free organocatalytic conjugate addition followed by a telescoped reductive amination–lactamiza...

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Xehetasun bibliografikoak
Argitaratua izan da:Chem Sci
Egile Nagusiak: Ötvös, Sándor B., Pericàs, Miquel A., Kappe, C. Oliver
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Royal Society of Chemistry 2019
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7069365/
https://ncbi.nlm.nih.gov/pubmed/32206263
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04752b
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