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Studies of lincosamide formation complete the biosynthetic pathway for lincomycin A

The structure of lincomycin A consists of the unusual eight-carbon thiosugar core methyllincosamide (MTL) decorated with a pendent N-methylprolinyl moiety. Previous studies on MTL biosynthesis have suggested GDP-ᴅ-erythro-α-ᴅ-gluco-octose and GDP-ᴅ-α-ᴅ-lincosamide as key intermediates in the pathway...

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Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Wang, Shao-An, Lin, Chia-I, Zhang, Jiawei, Ushimaru, Richiro, Sasaki, Eita, Liu, Hung-wen
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7547251/
https://ncbi.nlm.nih.gov/pubmed/32958639
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.2009306117
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