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Shallow Distance Dependence for Proton-Coupled Tyrosine Oxidation in Oligoproline Peptides

We have explored the kinetic effect of increasing electron transfer (ET) distance in a biomimetic, proton-coupled electron-transfer (PCET) system. Biological ET often occurs simultaneously with proton transfer (PT) in order to avoid the high-energy, charged intermediates resulting from the stepwise...

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Bibliografiska uppgifter
I publikationen:J Am Chem Soc
Huvudupphovsmän: Koronkiewicz, Brian, Swierk, John, Regan, Kevin, Mayer, James M.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2020
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7545454/
https://ncbi.nlm.nih.gov/pubmed/32510937
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c01429
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