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Shallow Distance Dependence for Proton-Coupled Tyrosine Oxidation in Oligoproline Peptides
We have explored the kinetic effect of increasing electron transfer (ET) distance in a biomimetic, proton-coupled electron-transfer (PCET) system. Biological ET often occurs simultaneously with proton transfer (PT) in order to avoid the high-energy, charged intermediates resulting from the stepwise...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7545454/ https://ncbi.nlm.nih.gov/pubmed/32510937 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c01429 |
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