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Theoretical Study of Shallow Distance Dependence of Proton-Coupled Electron Transfer in Oligoproline Peptides

Long-range electron transfer is coupled to proton transfer in a wide range of chemically and biologically important processes. Recently the proton-coupled electron transfer (PCET) rate constants for a series of biomimetic oligoproline peptides linking Ru(bpy)(3)(2+) to tyrosine were shown to exhibit...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Li, Pengfei, Soudackov, Alexander V., Koronkiewicz, Brian, Mayer, James M., Hammes-Schiffer, Sharon
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7544512/
https://ncbi.nlm.nih.gov/pubmed/32664731
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c04716
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