Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with dppf-Nickel(0)

[Image: see text] The mechanism of the reactions between dppf-Ni(0) complexes and alkyl halides has been investigated using kinetic and mechanistic experiments and DFT calculations. The active species is [Ni(κ(2)-dppf)(κ(1)-dppf)], which undergoes a halide abstraction reaction with alkyl halides and...

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Vydáno v:ACS Catal
Hlavní autoři: Greaves, Megan E., Ronson, Thomas O., Lloyd-Jones, Guy C., Maseras, Feliu, Sproules, Stephen, Nelson, David J.
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2020
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7507766/
https://ncbi.nlm.nih.gov/pubmed/32983589
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c02514
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