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Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with dppf-Nickel(0)
[Image: see text] The mechanism of the reactions between dppf-Ni(0) complexes and alkyl halides has been investigated using kinetic and mechanistic experiments and DFT calculations. The active species is [Ni(κ(2)-dppf)(κ(1)-dppf)], which undergoes a halide abstraction reaction with alkyl halides and...
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| 發表在: | ACS Catal |
|---|---|
| Main Authors: | , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
American
Chemical Society
2020
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| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7507766/ https://ncbi.nlm.nih.gov/pubmed/32983589 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c02514 |
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