Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged U(IV)/U(IV) Pacman complex

The oxo- and catecholate-bridged U(IV)/U(IV) Pacman complex [{(py)U(IV)OU(IV)(μ-O(2)C(6)H(4))(py)}(L(A))] A (L(A) = a macrocyclic “Pacman” ligand; anthracenylene hinge between N(4)-donor pockets, ethyl substituents on meso-carbon atom of each N(4)-donor pocket) featuring a bent U(IV)–O–U(IV) oxo bri...

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Udgivet i:Chem Sci
Main Authors: Cowie, Bradley E., Douair, Iskander, Maron, Laurent, Love, Jason B., Arnold, Polly L.
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2020
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7499863/
https://ncbi.nlm.nih.gov/pubmed/33033607
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02297g
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