Isocyanide and Phosphine Oxide Coordination in Binuclear Chromium Pacman Complexes

[Image: see text] The new binuclear chromium Pacman complex [Cr(2)(L)] of the Schiff base pyrrole macrocycle H(4)L has been synthesized and structurally characterized. Addition of isocyanide, C≡NR (R = xylyl, (t)Bu), or triphenylphosphine oxide donors to [Cr(2)(L)] gives contrasting chemistry with t...

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Bibliographic Details
Main Authors: Stevens, Charlotte J., Nichol, Gary S., Arnold, Polly L., Love, Jason B.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2013
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3905932/
https://ncbi.nlm.nih.gov/pubmed/24489428
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om4009313
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