Rapid Optical Determination of Enantiomeric Excess, Diastereomeric Excess, and Total Concentration Using Dynamic-Covalent Assemblies: A Demonstration Using 2‑Aminocyclohexanol and Chemometrics

Optical analysis of reaction parameters such as enantiomeric excess (ee), diastereomeric excess (de), and yield are becoming increasingly useful as assays for differing functional groups become available. These assays typically exploit reversible covalent or noncovalent assemblies that impart optica...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Herrera, Brenden T., Moor, Sarah R., McVeigh, Matthew, Roesner, Emily K., Marini, Federico, Anslyn, Eric V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497656/
https://ncbi.nlm.nih.gov/pubmed/31251589
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b03844
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