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Triarylborane‐Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds

Herein we report a facile, mild reaction protocol to form carbon–carbon bonds in the absence of transition metal catalysts. We demonstrate the metal‐free alkenylation reactions of aryl esters with α‐diazoesters to give highly functionalized enyne products. Catalytic amounts of tris(pentafluorophenyl...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Dasgupta, Ayan, Stefkova, Katarína, Babaahmadi, Rasool, Gierlichs, Lukas, Ariafard, Alireza, Melen, Rebecca L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497215/
https://ncbi.nlm.nih.gov/pubmed/32485034
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202007176
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