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Palladium Catalyzed β-Arylation of α-Keto Esters
A catalyst system derived from commercially available Pd(2)(dba)(3) and P(t)Bu(3) has been applied to the coupling of α–keto ester enolates and aryl bromides. The reaction provides access to an array of β–stereogenic α–keto esters. When the air stable ligand precursor P(t)Bu(3)·HBF(4) is employed, t...
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| 出版年: | Org Lett |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5598777/ https://ncbi.nlm.nih.gov/pubmed/28397500 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00761 |
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