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Direct Zinc(II)-Catalyzed Enantioconvergent Additions of Terminal Alkynes to α-Keto Esters
The addition of terminal alkynes to racemic β-stereogenic α-keto esters was achieved in high levels of stereoselectivity, affording versatile tertiary propargylic alcohols containing two stereocenters. This environmentally benign enantioconvergent reaction proceeds with perfect atom economy, require...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2017
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5554871/ https://ncbi.nlm.nih.gov/pubmed/28557339 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704226 |
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