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Triarylborane‐Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds

Herein we report a facile, mild reaction protocol to form carbon–carbon bonds in the absence of transition metal catalysts. We demonstrate the metal‐free alkenylation reactions of aryl esters with α‐diazoesters to give highly functionalized enyne products. Catalytic amounts of tris(pentafluorophenyl...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Dasgupta, Ayan, Stefkova, Katarína, Babaahmadi, Rasool, Gierlichs, Lukas, Ariafard, Alireza, Melen, Rebecca L.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497215/
https://ncbi.nlm.nih.gov/pubmed/32485034
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202007176
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