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Hypervalent Iodine(III)‐Catalysed Enantioselective α‐Acetoxylation of Ketones

An enantioselective catalytic synthesis of α‐acetoxylated ketones through I(I)/I(III) catalysis using a resorcinol/lactamide‐based chiral iodoarene is reported. Catalyst turnover by in situ generation of the active iodine(III) derivative is achieved by oxidation with mCPBA in the presence of acetic...

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Detaylı Bibliyografya
Yayımlandı:Chemistry
Asıl Yazarlar: Hokamp, Tobias, Wirth, Thomas
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: John Wiley and Sons Inc. 2020
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496773/
https://ncbi.nlm.nih.gov/pubmed/32233006
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000927
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