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Hypervalent Iodine(III)‐Catalysed Enantioselective α‐Acetoxylation of Ketones
An enantioselective catalytic synthesis of α‐acetoxylated ketones through I(I)/I(III) catalysis using a resorcinol/lactamide‐based chiral iodoarene is reported. Catalyst turnover by in situ generation of the active iodine(III) derivative is achieved by oxidation with mCPBA in the presence of acetic...
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| Udgivet i: | Chemistry |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7496773/ https://ncbi.nlm.nih.gov/pubmed/32233006 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000927 |
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