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Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents

A stereoselective hypervalent iodine‐promoted oxidative rearrangement of 1,1‐disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α‐arylated ketones without the use of transition metals from readily accessible alkenes.

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Brown, Michael, Kumar, Ravi, Rehbein, Julia, Wirth, Thomas
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797713/
https://ncbi.nlm.nih.gov/pubmed/26800241
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201504844
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