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Facile Oxidative Rearrangements Using Hypervalent Iodine Reagents

Aromatic substituents migrate in a novel oxidative cyclization mediated by iodine(III) reagents. 4-Arylbut-3-enoic acids are cyclized and rearranged to 4-arylfuran-2(5H)-ones by hypervalent iodine compounds in good to excellent yields under mild reaction conditions. Other ring sizes are also accessi...

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Autors principals: Singh, Fateh V, Rehbein, Julia, Wirth, Thomas
Format: Artigo
Idioma:Inglês
Publicat: WILEY-VCH Verlag 2012
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3922481/
https://ncbi.nlm.nih.gov/pubmed/24551514
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201200037
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