Hypervalent Iodine-Mediated Diastereoselective α-Acetoxylation of Cyclic Ketones

A binary hybrid system comprising a hypervalent iodine(III) reagent and BF(3)•OEt(2) Lewis acid was found to be effective for the diastereoselective α-acetoxylation of cyclic ketones. In this hybrid system, BF(3)•OEt(2) Lewis acid allowed the activation of the hypervalent iodine(III) reagent and cyc...

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Dettagli Bibliografici
Pubblicato in:Front Chem
Autori principali: Tan, Jiashen, Zhu, Weiqin, Xu, Weiping, Jing, Yaru, Ke, Zhuofeng, Liu, Yan, Maruoka, Keiji
Natura: Artigo
Lingua:Inglês
Pubblicazione: Frontiers Media S.A. 2020
Soggetti:
Chemistry
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7365914/
https://ncbi.nlm.nih.gov/pubmed/32754572
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2020.00467
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