Photoinduced and Thermal Single‐Electron Transfer to Generate Radicals from Frustrated Lewis Pairs

Archetypal phosphine/borane frustrated Lewis pairs (FLPs) are famed for their ability to activate small molecules. The mechanism is generally believed to involve two‐electron processes. However, the detection of radical intermediates indicates that single‐electron transfer (SET) generating frustrate...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Holtrop, Flip, Jupp, Andrew R., van Leest, Nicolaas P., Paradiz Dominguez, Maximilian, Williams, René M., Brouwer, Albert M., de Bruin, Bas, Ehlers, Andreas W., Slootweg, J. Chris
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496419/
https://ncbi.nlm.nih.gov/pubmed/32259331
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001494
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