Photoinduced and Thermal Single‐Electron Transfer to Generate Radicals from Frustrated Lewis Pairs

Archetypal phosphine/borane frustrated Lewis pairs (FLPs) are famed for their ability to activate small molecules. The mechanism is generally believed to involve two‐electron processes. However, the detection of radical intermediates indicates that single‐electron transfer (SET) generating frustrate...

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Publicat a:Chemistry
Autors principals: Holtrop, Flip, Jupp, Andrew R., van Leest, Nicolaas P., Paradiz Dominguez, Maximilian, Williams, René M., Brouwer, Albert M., de Bruin, Bas, Ehlers, Andreas W., Slootweg, J. Chris
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496419/
https://ncbi.nlm.nih.gov/pubmed/32259331
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001494
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