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Efficient [(NHC)Au(NTf(2))]-catalyzed hydrohydrazidation of terminal and internal alkynes

The efficient hydrohydrazidation of terminal (6a–r, 18 examples, 0.1–0.2 mol % [(NHC)Au(NTf(2))], T = 60 °C) and internal alkynes (7a–j, 10 examples, 0.2–0.5 mol % [(NHC)Au(NTf(2))], T = 60–80 °C) utilizing a complex with a sterically demanding bispentiptycenyl-substituted NHC ligand and the benign...

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Bibliografske podrobnosti
izdano v:Beilstein J Org Chem
Main Authors: Heidrich, Maximillian, Plenio, Herbert
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7476583/
https://ncbi.nlm.nih.gov/pubmed/32952724
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.175
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