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Efficient [(NHC)Au(NTf(2))]-catalyzed hydrohydrazidation of terminal and internal alkynes
The efficient hydrohydrazidation of terminal (6a–r, 18 examples, 0.1–0.2 mol % [(NHC)Au(NTf(2))], T = 60 °C) and internal alkynes (7a–j, 10 examples, 0.2–0.5 mol % [(NHC)Au(NTf(2))], T = 60–80 °C) utilizing a complex with a sterically demanding bispentiptycenyl-substituted NHC ligand and the benign...
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| Publicado no: | Beilstein J Org Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7476583/ https://ncbi.nlm.nih.gov/pubmed/32952724 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.175 |
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