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Au-Catalyzed Synthesis of 2-Alkylindoles from N-Arylhydroxylamines and Terminal Alkynes

The first gold-catalyzed addition of N-arylhydroxylamines to aliphatic terminal alkynes is developed to access O-alkenyl-N-arylhydroxylamines, which undergo facile in situ sequential 3,3-rearrangements and cyclodehydrations to afford 2-alkylindoles with regiospecificity and under exceptionally mild...

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Détails bibliographiques
Auteurs principaux: Wang, Yanzhao, Ye, Longwu, Zhang, Liming
Format: Artigo
Langue:Inglês
Publié: 2011
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3402563/
https://ncbi.nlm.nih.gov/pubmed/21637891
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c1cc12212f
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