Loading...

Diastereoselective peroxidation of derivatives of Baylis–Hillman adducts

Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.

Saved in:
Bibliographic Details
Published in:Tetrahedron
Main Authors: Zuckerman, Dylan S., Woerpel, K. A.
Format: Artigo
Language:Inglês
Published: 2019
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7437930/
https://ncbi.nlm.nih.gov/pubmed/32831414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2019.05.008
Tags: Add Tag
No Tags, Be the first to tag this record!