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Diastereoselective peroxidation of derivatives of Baylis–Hillman adducts

Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Tetrahedron
Egile Nagusiak: Zuckerman, Dylan S., Woerpel, K. A.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2019
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7437930/
https://ncbi.nlm.nih.gov/pubmed/32831414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2019.05.008
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