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Quinone methide dimers lacking labile hydrogen atoms are surprisingly excellent radical-trapping antioxidants

Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond is the key structural feature which underlies the reactivity of phenolic RTAs. We recently observed th...

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Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Raycroft, Mark A. R., Chauvin, Jean-Philippe R., Galliher, Matthew S., Romero, Kevin J., Stephenson, Corey R. J., Pratt, Derek A.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7422964/
https://ncbi.nlm.nih.gov/pubmed/32832049
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02020f
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