Quinone methide dimers lacking labile hydrogen atoms are surprisingly excellent radical-trapping antioxidants

Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond is the key structural feature which underlies the reactivity of phenolic RTAs. We recently observed th...

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Bibliographische Detailangaben
Veröffentlicht in:Chem Sci
Hauptverfasser: Raycroft, Mark A. R., Chauvin, Jean-Philippe R., Galliher, Matthew S., Romero, Kevin J., Stephenson, Corey R. J., Pratt, Derek A.
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2020
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7422964/
https://ncbi.nlm.nih.gov/pubmed/32832049
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02020f
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