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Quinone methide dimers lacking labile hydrogen atoms are surprisingly excellent radical-trapping antioxidants

Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond is the key structural feature which underlies the reactivity of phenolic RTAs. We recently observed th...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Raycroft, Mark A. R., Chauvin, Jean-Philippe R., Galliher, Matthew S., Romero, Kevin J., Stephenson, Corey R. J., Pratt, Derek A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7422964/
https://ncbi.nlm.nih.gov/pubmed/32832049
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02020f
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