Electrochemical Dimerization of Phenylpropenoids and the Surprising Antioxidant Activity of the Resultant Quinone Methide Dimers

A simple method for the dimerization of phenylpropenoid derivatives is reported. It leverages electrochemical oxidation of p-unsaturated phenols to access the dimeric materials in a biomimetic fashion. The mild nature of the transformation provides excellent functional group tolerance, resulting in...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Romero, Kevin J., Galliher, Matthew S., Raycroft, Mark A. R., Chauvin, Jean-Philippe R., Bosque, Irene, Pratt, Derek A., Stephenson, Corey R. J.
Format: Artigo
Idioma:Inglês
Publicat: 2018
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6309223/
https://ncbi.nlm.nih.gov/pubmed/30474921
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201810870
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