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Selective preparation of tetrasubstituted fluoroalkenes by fluorine-directed oxetane ring-opening reactions

The selective ring-opening reaction of fluoroalkylidene-oxetanes was directed by the presence of the fluorine atom, enabling a two-step access to tetrasubstituted fluoroalkenes with excellent geometry control. Despite its small van der Waals radii electronic, rather than steric influences of the flu...

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Xehetasun bibliografikoak
Argitaratua izan da:Beilstein J Org Chem
Egile Nagusiak: Fontenelle, Clément Q, Thierry, Thibault, Laporte, Romain, Pfund, Emmanuel, Lequeux, Thierry
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Beilstein-Institut 2020
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7418098/
https://ncbi.nlm.nih.gov/pubmed/32802210
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.160
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