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H12461. Fluorine as a Regiocontrol Element in the Ring Openings of Bicyclic Aziridiniums
The origin of the variation in the regioselectivity of the nucleophilic ring-opening of a series of bicyclic aziridinium ions derived from N-alkylprolinols was investigated by quantum chemical computations (M06-2X/6-31+G(d,p)—SMD). These aziridiniums differ only in the degree and the stereochemistry...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3586746/ https://ncbi.nlm.nih.gov/pubmed/23471532 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/hlca.201200461 |
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