Dehydropolymerisation of Methylamine Borane and an N‐Substituted Primary Amine Borane Using a PNP Fe Catalyst

Dehydropolymerisation of methylamine borane (H(3)B⋅NMeH(2)) using the well‐known iron amido complex [(PNP)Fe(H)(CO)] (PNP=N(CH(2)CH(2)PiPr(2))(2)) (1) gives poly(aminoborane)s by a chain‐growth mechanism. In toluene, rapid dehydrogenation of H(3)B⋅NMeH(2) following first‐order behaviour as a limitin...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Anke, Felix, Boye, Susanne, Spannenberg, Anke, Lederer, Albena, Heller, Detlef, Beweries, Torsten
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383739/
https://ncbi.nlm.nih.gov/pubmed/32118328
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000809
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