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Dehydropolymerisation of Methylamine Borane and an N‐Substituted Primary Amine Borane Using a PNP Fe Catalyst
Dehydropolymerisation of methylamine borane (H(3)B⋅NMeH(2)) using the well‐known iron amido complex [(PNP)Fe(H)(CO)] (PNP=N(CH(2)CH(2)PiPr(2))(2)) (1) gives poly(aminoborane)s by a chain‐growth mechanism. In toluene, rapid dehydrogenation of H(3)B⋅NMeH(2) following first‐order behaviour as a limitin...
Tallennettuna:
| Julkaisussa: | Chemistry |
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| Päätekijät: | , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
John Wiley and Sons Inc.
2020
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7383739/ https://ncbi.nlm.nih.gov/pubmed/32118328 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000809 |
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