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Step-growth titanium-catalysed dehydropolymerisation of amine–boranes

Precatalysts active for the dehydropolymerisation of primary amine–boranes are generally based on mid or late transition metal. We have found that the activity of the precatalyst system formed from Cp(R)(2)TiCl(2) and 2nBuLi towards the dehydrogenation of the secondary amine–borane Me(2)NH·BH(3), to...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Jurca, Titel, Dellermann, Theresa, Stubbs, Naomi E., Resendiz-Lara, Diego A., Whittell, George R., Manners, Ian
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5933219/
https://ncbi.nlm.nih.gov/pubmed/29780466
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05395a
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