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Step-growth titanium-catalysed dehydropolymerisation of amine–boranes

Precatalysts active for the dehydropolymerisation of primary amine–boranes are generally based on mid or late transition metal. We have found that the activity of the precatalyst system formed from Cp(R)(2)TiCl(2) and 2nBuLi towards the dehydrogenation of the secondary amine–borane Me(2)NH·BH(3), to...

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Publicat a:Chem Sci
Autors principals: Jurca, Titel, Dellermann, Theresa, Stubbs, Naomi E., Resendiz-Lara, Diego A., Whittell, George R., Manners, Ian
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5933219/
https://ncbi.nlm.nih.gov/pubmed/29780466
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05395a
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