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Step-growth titanium-catalysed dehydropolymerisation of amine–boranes

Precatalysts active for the dehydropolymerisation of primary amine–boranes are generally based on mid or late transition metal. We have found that the activity of the precatalyst system formed from Cp(R)(2)TiCl(2) and 2nBuLi towards the dehydrogenation of the secondary amine–borane Me(2)NH·BH(3), to...

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Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Jurca, Titel, Dellermann, Theresa, Stubbs, Naomi E., Resendiz-Lara, Diego A., Whittell, George R., Manners, Ian
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5933219/
https://ncbi.nlm.nih.gov/pubmed/29780466
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05395a
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