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Step-growth titanium-catalysed dehydropolymerisation of amine–boranes
Precatalysts active for the dehydropolymerisation of primary amine–boranes are generally based on mid or late transition metal. We have found that the activity of the precatalyst system formed from Cp(R)(2)TiCl(2) and 2nBuLi towards the dehydrogenation of the secondary amine–borane Me(2)NH·BH(3), to...
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| 發表在: | Chem Sci |
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| Main Authors: | , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Royal Society of Chemistry
2018
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5933219/ https://ncbi.nlm.nih.gov/pubmed/29780466 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05395a |
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