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Step-growth titanium-catalysed dehydropolymerisation of amine–boranes
Precatalysts active for the dehydropolymerisation of primary amine–boranes are generally based on mid or late transition metal. We have found that the activity of the precatalyst system formed from Cp(R)(2)TiCl(2) and 2nBuLi towards the dehydrogenation of the secondary amine–borane Me(2)NH·BH(3), to...
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| Publicado en: | Chem Sci |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5933219/ https://ncbi.nlm.nih.gov/pubmed/29780466 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05395a |
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