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Effect of the Phosphine Steric and Electronic Profile on the Rh-Promoted Dehydrocoupling of Phosphine–Boranes
[Image: see text] The electronic and steric effects in the stoichiometric dehydrocoupling of secondary and primary phosphine–boranes H(3)B·PR(2)H [R = 3,5-(CF(3))(2)C(6)H(3); p-(CF(3))C(6)H(4); p-(OMe)C(6)H(4); adamantyl, Ad] and H(3)B·PCyH(2) to form the metal-bound linear diboraphosphines H(3)B·PR...
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| Main Authors: | , , , , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3979130/ https://ncbi.nlm.nih.gov/pubmed/24617924 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic500032f |
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