Effect of the Phosphine Steric and Electronic Profile on the Rh-Promoted Dehydrocoupling of Phosphine–Boranes

[Image: see text] The electronic and steric effects in the stoichiometric dehydrocoupling of secondary and primary phosphine–boranes H(3)B·PR(2)H [R = 3,5-(CF(3))(2)C(6)H(3); p-(CF(3))C(6)H(4); p-(OMe)C(6)H(4); adamantyl, Ad] and H(3)B·PCyH(2) to form the metal-bound linear diboraphosphines H(3)B·PR...

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Bibliografiske detaljer
Main Authors: Hooper, Thomas N., Huertos, Miguel A., Jurca, Titel, Pike, Sebastian D., Weller, Andrew S., Manners, Ian
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2014
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3979130/
https://ncbi.nlm.nih.gov/pubmed/24617924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic500032f
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