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Development and Mechanistic Interrogation of Interrupted Chain-Walking in the Enantioselective Relay Heck Reaction

The formation of alkyl–palladium complexes via the nucleopalladation of alkenes is the entry point for a wide range of diverse reactions. One possibility is that the intermediate alkyl–Pd complexes can undergo a “chain-walking” event, to allow for remote functionalization through various termination...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Ross, Sean P., Rahman, Ajara A., Sigman, Matthew S.
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7376753/
https://ncbi.nlm.nih.gov/pubmed/32412759
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03589
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