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Development and Mechanistic Interrogation of Interrupted Chain-Walking in the Enantioselective Relay Heck Reaction
The formation of alkyl–palladium complexes via the nucleopalladation of alkenes is the entry point for a wide range of diverse reactions. One possibility is that the intermediate alkyl–Pd complexes can undergo a “chain-walking” event, to allow for remote functionalization through various termination...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7376753/ https://ncbi.nlm.nih.gov/pubmed/32412759 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03589 |
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