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Mechanism-Guided Design and Discovery of Efficient Cytochrome P450-Derived C—H Amination Biocatalysts

Cytochromes P450 have been recently identified as a promising class of biocatalysts for mediating C—H aminations via nitrene transfer, a valuable transformation for forging new C—N bonds. The catalytic efficiency of P450s in these non-native transformations is however significantly inferior to that...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Steck, Viktoria, Kolev, Joshua N., Ren, Xinkun, Fasan, Rudi
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7372717/
https://ncbi.nlm.nih.gov/pubmed/32407077
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b12859
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