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Catalytic Asymmetric Staudinger–aza-Wittig Reaction for the Synthesis of Heterocyclic Amines
Many natural products and medicinal drugs are heterocyclic amines possessing a chiral quaternary carbon atom in their heterocyclic ring. Herein, we report the first catalytic and asymmetric Staudinger–aza-Wittig reaction for the desymmetrization of ketones. This highly enantioselective transformatio...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7371345/ https://ncbi.nlm.nih.gov/pubmed/31184143 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b04803 |
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