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Sulfamyl Radicals Direct Photoredox-Mediated Giese Reactions at Unactivated C(3)–H Bonds
Alcohol-anchored sulfamate esters guide the alkylation of tertiary and secondary aliphatic C(3)–H bonds. The transformation proceeds directly from N–H bonds with a catalytic oxidant, a contrast to prior methods which have required pre-oxidation of the reactive nitrogen center, or employed stoichiome...
Tallennettuna:
| Julkaisussa: | Org Lett |
|---|---|
| Päätekijät: | , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2019
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7359209/ https://ncbi.nlm.nih.gov/pubmed/31313933 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b02234 |
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